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Barbara (Monet Mazur) is an operative for Volkoff Industries who appears in "Chuck Versus the Leftovers" as part of the team lead by Alexei Volkoff on an invasion of the Burbank Buy More. Throughout the episode, she acts as Volkoff's second-in-command, carrying out his orders.

She gets the team access to the Buy More by pretending to be a customer seeking out a Bondesen 7G smart phone, offering to do 'anything' for the staff if they let her in. Jeff succumbs to her plea.

Barbara is last seen guarding Casey who is Volkoff's hostage, when Alexei gives informs her that their mission is accomplished and to stand down.